Plasma Electrolytic Oxide Coatings on Silumin for Oxidation CO

Some catalysts of CO oxidation on silumin alloy AK12M2, used for the manufacture of pistons for Russian cars were investigated. The catalysts were prepared by the method of plasma electrolytic oxidation of silumin in electrolytes of various compositions with further activation by the salts Ce, Cu, Co, Ni, Mn and Al. The catalytic tests were carried out in a flow reactor in a mixture of 1% CO and 99% air, with the temperature range of 25-500 °C. The most active catalysts in CO oxidation are those activated with Ce and Cu salts on silumin, treated for 3 hours in an electrolyte containing 4 g/l KOH, 40 g/l Na2B4O7 (conversion of CO is 93.7% at a contact time of 0.25 s). However, the catalysts obtained from silumin treated in the electrolyte containing 3 g/l KOH, 30 g/l Na2SiO3 are more suitable for practical usage. Because when the treatment time of those catalysts is 10 – 20 minutes it is possible to achieve comparable CO conversion. The morphology and composition of the catalysts were studied by the methods of a scanning electron microscope with energy-dispersive surface analysis and X-ray phase analysis. The surface of the non-activated sample consists of γ-Al2O3 and SiO2 particles, due to which the active components get attached to the support. CeO2 and CuO are present on the surface of the sample with the active component.

Химическая технология. Химическая промышленность

Вуз: Омский государственный университет путей сообщения

ID: 5b1fc9437966e104dde3e323
UUID: afa70480-5071-0136-e4b9-525400005860
Язык: Английский
Опубликовано: 2 месяца назад
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Павел Литвинов

Сибирская государственная автомобильно-дорожная академия (СибАДИ) (ФГБОУ ВПО СибАДИ)


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